Dissolution
is the physical process of dissolving a solute in a solvent without any
chemical reaction taking place. In the case of gases, their insolubility in
liquids can be easily explained. Since gas molecules are far apart, the force
of attraction among their own molecules is negligible, and they will also have
a negligible force of attraction for liquid solvents. Consequently, gases will
have lower solubility in liquid solvents.
However,
under certain circumstances, gases can become soluble in liquids, especially at
high pressures. As pressure increases, solubility increases as well.
Occasionally, the solubility rate of gases in liquids can be rapid due to the
chemical reaction between the liquids and gases.
Cohesive
forces exist not only among solute molecules but also among solvent molecules.
These forces are responsible for keeping the molecules of a substance held
together. The dissolution process can only occur if the solvent molecules
overcome the cohesive forces among the solute molecules. In other words, the
force of attraction between the molecules of solvent and solute must be greater
than the force of attraction between the solute's molecules.
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