Electrolysis of water is the
chemical reaction that occurs when an electric current is passed through a
solution of water, resulting in the decomposition of water molecules into their
constituent elements: hydrogen and oxygen.
The reaction takes place in
an electrolysis cell, which consists of two electrodes (an anode and a cathode)
and a solution of water (which acts as an electrolyte). The anode is typically
made of an inert material such as platinum or carbon, while the cathode can be
made of a variety of metals.
When an electric current is
passed through the water, the anode becomes positively charged and the cathode
becomes negatively charged. This causes the water molecules to dissociate into
their constituent ions: hydrogen ions (H+) are attracted to the cathode, while
hydroxide ions (OH-) are attracted to the anode.
At the cathode, hydrogen
ions gain electrons from the electric current and are reduced to form hydrogen
gas (H2):
2H+ + 2e- → H2
At the anode, hydroxide ions
lose electrons to the electric current and are oxidized to form oxygen gas
(O2):
4OH- → 2H2O + O2 + 4e-
Overall, the balanced
equation for the electrolysis of water is:
2H2O → 2H2 + O2
The process of electrolysis
can be used to generate hydrogen and oxygen gas for a variety of applications,
including fuel cells and chemical synthesis. It can also be used to purify
water and remove impurities, as the electric current can break down many types
of contaminants into their constituent ions.
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